Monday, 19th May 2014
| Contestants | New Songs Round (2006-) |
| Pravasthi | Mudhal Murai (Neethaane En Ponvasantham) |
| Jessica | Innum Konjam Neram (Maryan) |
| Charan | Ayayayoo Aananthamey (Kumki) |
| Sonika | Kacheri Kacheri (Kacheri Arambam) |
| Srihari | Thuli Thuli Mazhaiyaai (Paiyaa) |
| Contestants | New Songs Round (2006-) |
| Spoorthi | Azhagaai Pookkuthey (Ninaithale Inikkum) |
| Rohini | Pesugiren Pesugiren (Satham Podathey) |
| Angeline | Vaada Maappilley (Villu) |
| Anal Akash | Koodamela Koodavechi (Rummy) |
| Krishna Sai | Oru Paadhi Kadhavu (Thaandavam) |
Contestants | New Songs Round (2006-) |
Arjun | Boomi Enna Suthudhe (Ethir Neechal) |
Haripriya | Ammadi Ammadi (Desingu Raja) |
Anushya | Vizhigalil Oru Vaanavil (Deiva Thirumagal) |
Karthika | Mayam Seidhayo (Velayudham) |
Mohammed | Naane Indhiran (Singam) |
Contestants | New Songs Round (2006-) |
Robin | Kaatrin Mozhi (Mozhi) |
Srisha | Enadhuyire (Bheema) |
Nazim | Yamma Yamma (7am Arivu) |
Aishwarya | Munbe Vaa (Sillunu Oru Kaadhal) |
Monika | Puriyavillai (Singam II) |
Friday, 23rd May 2014
| Contestants | New Songs Round (2006-) |
| Priya | Kalvare Kalvare (Raavanan) |
| Sunantha | Mannipaaya (Vinnaaithaandi Varuvaaya) |
| Bharath | Bad Boy (Alex Pandian) |
| Shivani | Uruguthey Maruguthey (Veyil) |
| Kumudhini | Poraney Poraney (Vaagai Sooda Vaa) |
Danger zone: Jessica, Arjun, Charan, Anal Akash, Priya, Nazim
Anal Akash, Priya & Nazim called to the stage
Nazim eliminated
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