I think when he heard Ambalika's prediction....he was wondering as to why he would bite Arjun.
But remember as her well wisher he later comes to know that Masa has the mani, and Amrita doesn't know the Manter for it...he then realized he could force Masa to use the Mani on Arjun so that Amrita could get it.
He said he loved her....that's why he did it.
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