As per Devi Puran, Sati turns dark with anger.
She indeed takes Mahakaali form.Before leaving for yagya, Mahadev tries to stop her. At that time she appears as Dash Mahavidyas fro 10 different directions. When Mahadev asks her about these forms She explains of Mahakaali being her own form & other 9 Mahavidyas as her Vibhutis.Veerbhadra & Bhadrakaali are invoked by Mahadev from 2 strands of his jata, to destroy Daksh's yagya.
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